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1 article(s) from Hadad, Christopher M

On the mechanism of action of gated molecular baskets: The synchronicity of the revolving motion of gates and in/out trafficking of guests

Keith Hermann,
Stephen Rieth,
Hashem A. Taha,
Bao-Yu Wang,
Christopher M. Hadad and
Jovica D. Badjić

Beilstein J. Org. Chem. 2012, 8, 90–99, doi:10.3762/bjoc.8.9

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Figure 1: Chemical structure of gated molecular basket 1 and 1,1,1-trichloroethane (2). Electrostatic potenti...

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Figure 2: (Left): ¹H NMR spectra (400 MHZ, CD₂Cl₂) of 1 (0.67 mM) obtained upon incremental addition of 1,1,1...

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Figure 3: Chemically equivalent CH₃ protons (black) in 1,1,1-trichloroethane (2) alter their magnetic environ...

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Figure 4: Nonlinear least-squares fitting (SigmaPlot) of magnetization rate constants k*_in (2-D EXSY, 250.0 ±...

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Figure 5: (A): Nonlinear least-squares fitting of ¹H NMR signal intensities (I_in/out) of [CH₃CCl₃]_in/out as f...

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Figure 6: (A) Four different trajectories were used for examining the departure of CH₃CCl₃ guest from basket 1...

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Figure 7: (A) The interconversion of conformational enantiomers 1_A and 1_B, having anticlockwise and clockwise...

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Figure 8: The departure of CH₃CCl₃ from 1_A–CH₃CCl₃ gives rise to the less stable 1–CD₂Cl₂, which upon entrapm...

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Figure 9: (A): Kinetic and thermodynamic parameters [13,14] characterizing the departure of isosteric guests 3–7 fro...

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Published 16 Jan 2012

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